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・ Phosphorus (horse)
・ Phosphorus (morning star)
・ Phosphorus acid
・ Phosphorus and non-atherosclerotic heart disease
・ Phosphorus bromide
・ Phosphorus chloride
・ Phosphorus cycle
・ Phosphorus deficiency
・ Phosphorus fluoride
・ Phosphorus halide
・ Phosphorus heptabromide
・ Phosphorus iodide
・ Phosphorus mononitride
・ Phosphorus nitride
・ Phosphorus oxide
Phosphorus pentabromide
・ Phosphorus pentachloride
・ Phosphorus pentafluoride
・ Phosphorus pentaiodide
・ Phosphorus pentasulfide
・ Phosphorus pentoxide
・ Phosphorus selenide
・ Phosphorus sesquisulfide
・ Phosphorus sulfide
・ Phosphorus tribromide
・ Phosphorus tribromide (data page)
・ Phosphorus trichloride
・ Phosphorus trichloride (data page)
・ Phosphorus trifluoride
・ Phosphorus trifluoride (data page)


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Phosphorus pentabromide : ウィキペディア英語版
Phosphorus pentabromide

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Phosphorus pentabromide is a reactive, yellow solid of formula PBr5, which has the structure PBr4+ Br in the solid state but in the vapor phase is completely dissociated to PBr3 and Br2. Rapid cooling of this phase to 15 K leads to formation of the ionic species ()+().
It can be used in organic chemistry to convert carboxylic acids to acyl bromides. It is highly corrosive. It decomposes above 100 °C to give phosphorus tribromide and bromine:
:PBr5PBr3 + Br2
Reversing this equilibrium to generate PBr5 by addition of Br2 to PBr3 is difficult in practice because the product is susceptible to further addition to yield PBr7.
== References ==



抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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